Structure and Intermolecular Interactions in Aqueous Solutions of Polyethylene Glycol

Almásy, L.; Artykulnyi, O.P.; Petrenko, V.I.; Ivankov, O.I.; Bulavin, L.A.; Yan, M.; Haramus, V.M.

Journalpaper

Structure and Intermolecular Interactions in Aqueous Solutions of Polyethylene Glycol

Abstract

Aqueous solutions of polyethylene glycol are studied by small-angle neutron scattering over a broad range of polymer molecular masses and concentrations. The scattering data were modeled by a Gaussian chain form factor combined with random phase approximation, which provided good fits over the whole studied concentration range. The results showed that polyethylene glycol in the molecular mass range 0.4–20 kDa in water at physiological temperature T = 37 ∘C behaves like a random coil in nearly theta solvent conditions. The obtained results serve as a reference for the description of complex mixtures with PEG used in various applications.

DOI Link to Publication

URL: https://publications.hereon.de/id/50522/
Authors:Almásy, L., Artykulnyi, O.P., Petrenko, V.I., Ivankov, O.I., Bulavin, L.A., Yan, M., Haramus, V.M.
Year:2022
In: Molecules
Volume:27
Issue:8
Pages:2573
Publisher:MDPI, Basel
Type:Journalpaper
ISSN: 1420-3049
Cite as: Almásy, L.; Artykulnyi, O.P.; Petrenko, V.I.; Ivankov, O.I.; Bulavin, L.A.; Yan, M.; Haramus, V.M.: Structure and Intermolecular Interactions in Aqueous Solutions of Polyethylene Glycol. In: Molecules. Vol. 27 (2022) 8, 2573. (DOI: /10.3390/molecules27082573)