@misc{pashayev_experimental__2023, 
author={Pashayev, E., Kandelhard, F., Georgopanos, P.},
title={Experimental & Modelling Digital Twin Approach for Polymer Synthesis via Re-initiated Oxygen inhibited RAFT Polymerization},
year={2023},
howpublished = {journal article},
doi = {https://doi.org/10.1002/mren.202200068},
abstract = {Controlled polymerization techniques like the reversible-addition fragmentation chain transfer polymerization (RAFT) are sensitive to impurities such as oxygen. This work explores the application of re-initiation as a tool to enhance monomer conversion. A kinetic model for the oxygen inhibited RAFT dispersion polymerization for the synthesis of poly(4-vinylpyridine)-b-polystyrene (P4VP-b-PS) is developed. Thus, using the kinetic model, the re-initiation of the inhibited RAFT polymerization is partially (monomer conversion ≤10%) predicted. By implementing the re-initiation as a solution the synthesis of P4VP-b-PS copolymers with the high conversion (>96%) and a good dispersity (≤1.2) is enabled.},
note = {Online available at: \url{https://doi.org/10.1002/mren.202200068} (DOI). Pashayev, E.; Kandelhard, F.; Georgopanos, P.: Experimental & Modelling Digital Twin Approach for Polymer Synthesis via Re-initiated Oxygen inhibited RAFT Polymerization. Macromolecular Reaction Engineering. 2023. vol. 17, no. 2, 2200068. DOI: 10.1002/mren.202200068}}