@misc{jacob_nitrite_consumption_2016, author={Jacob, J., Sanders, T., Daehnke, K.}, title={Nitrite consumption and associated isotope changes during a river flood event}, year={2016}, howpublished = {journal article}, doi = {https://doi.org/10.5194/bg-13-5649-2016}, abstract = {During the flood event, > 97 % of total reactive nitrogen was nitrate, which was leached from the catchment area and appeared to be subject to assimilation. Ammonium and nitrite concentrations increased to 3.4 and 4.4 µmol L−1, respectively, likely due to remineralisation, nitrification, and denitrification in the water column. δ15N–NH4+ values increased up to 12 ‰, and δ15N–NO2− ranged from −8.0 to −14.2 ‰. Based on this, we calculated an apparent isotope effect 15ε of −10.0 ± 0.1 ‰ during net nitrite consumption, as well as an isotope effect 15ε of −4.0 ± 0.1 ‰ and 18ε of −5.3 ± 0.1 ‰ during net nitrate consumption. On the basis of the observed nitrite isotope changes, we evaluated different nitrite uptake processes in a simple box model. We found that a regime of combined riparian denitrification and 22 to 36 % nitrification fits best with measured data for the nitrite concentration decrease and isotope increase.}, note = {Online available at: \url{https://doi.org/10.5194/bg-13-5649-2016} (DOI). Jacob, J.; Sanders, T.; Daehnke, K.: Nitrite consumption and associated isotope changes during a river flood event. Biogeosciences. 2016. vol. 13, no. 19, 5649-5659. DOI: 10.5194/bg-13-5649-2016}}