@misc{cao_new_synthesis_2016, author={Cao, H., Santoru, A., Pistidda, C., Richter, T.M.M., Chaudhary, A.-L., Gizer, G., Niewa, R., Chen, P., Klassen, T., Dornheim, M.}, title={New synthesis route for ternary transition metal amides as well as ultrafast amide–hydride hydrogen storage materials}, year={2016}, howpublished = {journal article}, doi = {https://doi.org/10.1039/C6CC00719H}, abstract = {K2[Mn(NH2)4] and K2[Zn(NH2)4] were successfully synthesized via a mechanochemical method. The mixture of K2[Mn(NH2)4] and LiH showed excellent rehydrogenation properties. In fact, after dehydrogenation K2[Mn(NH2)4]-8LiH fully rehydrogenates within 60 seconds at ca. 230 °C and 5 MPa of H2. This is one of the fastest rehydrogenation rates in amide–hydride systems known to date. This work also shows a strategy for the synthesis of transition metal nitrides by decomposition of the mixtures of M[M′(NH2)n] (where M is an alkali or alkaline earth metal and M′ is a transition metal) and metal hydrides.}, note = {Online available at: \url{https://doi.org/10.1039/C6CC00719H} (DOI). Cao, H.; Santoru, A.; Pistidda, C.; Richter, T.; Chaudhary, A.; Gizer, G.; Niewa, R.; Chen, P.; Klassen, T.; Dornheim, M.: New synthesis route for ternary transition metal amides as well as ultrafast amide–hydride hydrogen storage materials. Chemical Communications : ChemComm. 2016. vol. 52, no. 29, 5100-5103. DOI: 10.1039/C6CC00719H}}