@misc{suarezalcantara_synchrotron_diffraction_2015, author={Suarez-Alcantara, K., Soerby, M.H., Pistidda, C., Karimi, F., Saldan, I., Hauback, B.C., Klassen, T., Dornheim, M.}, title={Synchrotron Diffraction Studies of Hydrogen Absorption/Desorption on CaH2 + MgB2 Reactive Hydride Composite Mixed With Fluorinated Compounds}, year={2015}, howpublished = {journal article}, doi = {https://doi.org/10.1021/acs.jpcc.5b01961}, abstract = {The reactive hydride composites 9CaH2 + CaF2 + 10MgB2, 10Ca(BH4)2 + 9MgH2 + MgF2, and 9Ca(BH4)2 + Ca(BF4)2 + 10MgH2 were prepared by ball milling. Their properties toward hydrogen absorption/desorption were tested by means of manometric measurements. The highest hydrogen storage capacity was obtained for 9CaH2 + CaF2 + 10MgB2 (7.6 wt %) at the first cycle. The effects of CaF2, MgF2, or Ca(BF4)2 on the dehydrogenation reaction were studied by means of in situ synchrotron radiation powder X-ray diffraction (in situ SR-PXD) and differential scanning calorimetry (DSC). The high resolution SR-PXD technique was used to confirm the formation of hydrogenated products and side products in the 9CaH2 + CaF2 + 10MgB2 reactive hydride composites. These studies indicate the formation of a complex mixture of phases.}, note = {Online available at: \url{https://doi.org/10.1021/acs.jpcc.5b01961} (DOI). Suarez-Alcantara, K.; Soerby, M.; Pistidda, C.; Karimi, F.; Saldan, I.; Hauback, B.; Klassen, T.; Dornheim, M.: Synchrotron Diffraction Studies of Hydrogen Absorption/Desorption on CaH2 + MgB2 Reactive Hydride Composite Mixed With Fluorinated Compounds. The Journal of Physical Chemistry C. 2015. vol. 119, no. 21, 11430-11437. DOI: 10.1021/acs.jpcc.5b01961}}