@misc{zhang_shapememory_capability_2015, author={Zhang, Q., Sauter, T., Fang, L., Kratz, K., Lendlein, A.}, title={Shape-Memory Capability of Copolyetheresterurethane Microparticles Prepared via Electrospraying}, year={2015}, howpublished = {journal article}, doi = {https://doi.org/10.1002/mame.201400267}, abstract = {Multifunctional thermo-responsive and degradable microparticles exhibiting a shape-memory effect (SME) have attracted widespread interest in biomedicine as switchable delivery vehicles or microactuators. In this work almost spherical solid microparticles with an average diameter of 3.9 ± 0.9 μm are prepared via electrospraying of a copolyetheresterurethane named PDC, which is composed of crystallizable oligo(p-dioxanone) (OPDO) hard and oligo(ε-caprolactone) (OCL) switching segments. The PDC microparticles are programmed via compression at different pressures and their shape-memory capability is explored by off-line and online heating experiments. When a low programming pressure of 0.2 MPa is applied a pronounced thermally-induced shape-memory effect is achieved with a shape recovery ratio about 80%, while a high programming pressure of 100 MPa resulted in a weak shape-memory performance. Finally, it is demonstrated that an array of PDC microparticles deposited on a polypropylene (PP) substrate can be successfully programmed into a smart temporary film, which disintegrates upon heating to 60 °C.}, note = {Online available at: \url{https://doi.org/10.1002/mame.201400267} (DOI). Zhang, Q.; Sauter, T.; Fang, L.; Kratz, K.; Lendlein, A.: Shape-Memory Capability of Copolyetheresterurethane Microparticles Prepared via Electrospraying. Macromolecular Materials and Engineering. 2015. vol. 300, no. 5, 522-530. DOI: 10.1002/mame.201400267}}