%0 journal article
%@ 0032-3861
%A Heuchel, M.,Cui, J.,Kratz, K.,Kosmella, H.,Lendlein, A.
%D 2010
%J Polymer
%N 26
%P 6212-6218 
%R doi:10.1016/j.polymer.2010.10.051
%T Relaxation based modeling of tunable shape recovery kinetics observed under isothermal conditions for amorphous shape-memory polymers
%U https://doi.org/10.1016/j.polymer.2010.10.051
26 
%X Polymers, which allow the adjustment of shape-memory properties by variation of physical parameters during programming, are advantageous to their counterparts requiring synthesis of a new material.,Here we explored the stress relaxation behaviour of polyurethane (PEU) based shape-memory polymers at temperatures from 0 °C to 80 °C and different strain values from 100% to 250%. The obtained relaxation curves could be well described by a modified Maxwell–Weichert model of two Maxwell units and a spring. The stress relaxation results in a combination of a slow and a fast decaying process. For modeling the isothermal recovery of recently introduced PEU composite scaffolds at 37 °C the fast relaxation could be neglected resulting in a model of a standard linear solid, which was in good agreement with the experimental data.,The presented modeling approach might be helpful to define design criteria for self sufficiently moving scaffolds within a knowledge-based development process.