@misc{lahcini_syntheses_of_2010, author={Lahcini, M., Qayouh, H., Yashiro, T., Simon, P.F.W., Kricheldorf, H.R.}, title={Syntheses of Poly(butylene succinate) by Means of Non-Toxic Catalysts}, year={2010}, howpublished = {journal article}, doi = {https://doi.org/10.1080/10601321003741875}, abstract = {The usefulness of bismuth, calcium, magnesium and zinc salts for the preparation of poly(butylene succinate), PBSu, was studied. Two different approaches were compared. Firstly, 1,4-butanediol (or in a few experiments ethanediol) dimethyl succinate were condensed at temperatures up to 240°C in the presence of Bi2O3. Regardless of the feed ratio, only low molar mass polyesters having two diol endgroups were obtained. Secondly, 1,4-butanediol and succinic anhydride were polycondensed in refluxing decalin with azeotropic removal of water. BiCL3, BiBr3, BiI3, and Bi-triflate were used as catalyst and the monomer/catalyst ratio was varied. The highest molar masses were achieved with BiCl3. Analogous polycondensations catalysed with ZnCl2, Zn-triflate, MgCl2, Mg-triflate and CaCl2 were unsuccessful. Yet the BiCl3, decalin method was also successfully applied to the combination of succinic anhydride and 1,5-pentanediol.}, note = {Online available at: \url{https://doi.org/10.1080/10601321003741875} (DOI). Lahcini, M.; Qayouh, H.; Yashiro, T.; Simon, P.; Kricheldorf, H.: Syntheses of Poly(butylene succinate) by Means of Non-Toxic Catalysts. Journal of Macromolecular Science A. 2010. vol. 47, no. 6, 503-509. DOI: 10.1080/10601321003741875}}