@misc{zotzmann_amorphous_phasesegregated_2009, author={Zotzmann, J., Alteheld, A., Behl, M., Lendlein, A.}, title={Amorphous phase-segregated copoly(ether)esterurethane thermoset networks with oligo(propylene glycol) and oligo[(rac-lactide)-co-glycolide] segments: synthesis and characterization}, year={2009}, howpublished = {journal article}, doi = {https://doi.org/10.1007/s10856-009-3761-x}, abstract = {Completely amorphous copoly(ether)ester networks based on oligo(propylene glycol) and oligo[(rac-dilactide)-co-glycolide] segments were synthesized by crosslinking star-shaped hydroxyl-telechelic cooligomers using an aliphatic low-molecular weight diisocyanate. Two different network architectures were applied exhibiting differences in the phase-separation behavior. For networks from oligo(propylene glycol)-block-oligo[(rac-lactide)-co-glycolide] triols (G3OPG-bl-OLG) only one glass transition was obtained. However, networks from a mixture of oligo(propylene glycol) triols (G3OPG) and oligo[(rac-lactide)-co-glycolide] tetrols (P4OLG) with a ratio of components in a certain range show two glass transition temperatures (T g) being attributed to two segregated amorphous phases. In this way a wide spectrum of mechanical properties can be realized and adjusted to the requirements of a specific application.}, note = {Online available at: \url{https://doi.org/10.1007/s10856-009-3761-x} (DOI). Zotzmann, J.; Alteheld, A.; Behl, M.; Lendlein, A.: Amorphous phase-segregated copoly(ether)esterurethane thermoset networks with oligo(propylene glycol) and oligo[(rac-lactide)-co-glycolide] segments: synthesis and characterization. Journal of Materials Science: Materials in Medicine. 2009. vol. 20, no. 9, 1815-1824. DOI: 10.1007/s10856-009-3761-x}}