@article{yave_a_novel_2007, author={Yave, W. and Shishatskiy, S. and Abetz, V. and Matson, S. and Litvinova, E. and Khotimskiy, V. and Peinemann, K.-V.}, title={A Novel Poly(4-methyl-2-pentyne)/TiO2 Hybrid Nanocomposite Membrane for Natural Gas Conditioning: Butane/Methane Separation}, year={2007}, journal = {Macromolecular Chemistry and Physics}, volume = {208}, number = {22}, pages = {2412 - 2418}, doi = {http://dx.doi.org/10.1002/macp.200700399}, abstract = {Poly(4-methyl-2-pentyne) (PMP)/TiO2 hybrid nanocomposite membranes have been investigated for natural gas conditioning. Tailor-made PMP with 35% cis-content was identified as an attractive material to prepare nanocomposite membranes; it presented good stability towards organic vapors and optimal properties for butane/methane separation. The PMP/TiO2 hybrid nanocomposite membranes presented an improvement of butane permeability and butane/methane selectivity. The addition of TiO2 nanoparticles to the PMP enhanced the selectivity more effectively than fumed-silica, and it is attractively higher than those currently reported in the open literature.}, note = {Online available at: \url{http://dx.doi.org/10.1002/macp.200700399} (DOI). Yave, W.; Shishatskiy, S.; Abetz, V.; Matson, S.; Litvinova, E.; Khotimskiy, V.; Peinemann, K.-V.: A Novel Poly(4-methyl-2-pentyne)/TiO2 Hybrid Nanocomposite Membrane for Natural Gas Conditioning: Butane/Methane Separation. In: Macromolecular Chemistry and Physics. Vol. 208 (2007) 22, 2412 - 2418. (DOI: 10.1002/macp.200700399)}}