%0 Artikel %@ 0269-7491 %A Xie, Z. %A Lakaschus, S. %A Ebinghaus, R. %A Caba, A. %A Ruck, W. %D 2006 %J Environmental Pollution %N 2052 %P 170 - 180 %R doi:10.1016/j.envpol.2005.08.073 %T Atmospheric concentrations and air-sea exchanges of nonylphenol, tertiary octylphenol and nonylphenol monoethoxylate in the North Sea %U http://dx.doi.org/10.1016/j.envpol.2005.08.073 1 %X Concentrations of nonylphenol isomers (NP), tertiary octylphenol (t-OP) and nonylphenol monoethoxylate isomers (NP1EO) have been simultaneously determined in the sea water and atmosphere of the North Sea. A decreasing concentration profile appeared following the distance increasing from the coast to the central part of the North Sea. Air–sea exchanges of t-OP and NP were estimated using the two-film resistance model based upon relative air–water concentrations and experimentally derived Henry's law constant. The average of air–sea exchange fluxes was −12 ± 6 ng m−2 day−1 for t-OP and −39 ± 19 ng m−2 day−1 for NP, which indicates a net deposition is occurring. These results suggest that the air–sea vapour exchange is an important process that intervenes in the mass balance of alkylphenols in the North Sea.