@misc{prado_saxswaxs_characterization_2005, 
author={Prado, L.A.S. de A.,Ponce, M.L.,Funari, S.S.,Schulte, K.,Haramus, V.M.,Willumeit, R.,Pereira Nunes, S.},
title={SAXS/WAXS characterization of proton-conducting polymer membranes containing phosphomolybdic acid},
year={2005},
howpublished = {journal article},
doi = {https://doi.org/10.1016/j.jnoncrysol.2005.06.007},
abstract = {In the present paper the distribution of phosphomolybdic acid (PMoA,H 3PMo12O40) dispersed in sulfonated poly(ether ether ketone),SPEEK, was investigated by simultaneous small/wide-angle X-ray scattering SAXS/WAXS technique. The hydrolysis and condensation of 3-aminopropyltrimethoxysilane or zirconium tetrapropylate in these polymeric matrices were used to produce poly(3-aminopropyl silsesquioxane) or ZrO2,as nano-fillers. Contrary to previous results reported for membranes containing phosphotungstic acid,the PMoA coalesced into mass-fractal structure,with fractal-dimension 1.85. The largest fractal aggregate was about 524 A˚ . Moreover,WAXS curves evidenced the crystallization of this heteropolyacid during the casting process. No changes concerning the distribution of PMoA were observed in the membranes containing SPEEK,PMoA and the poly(3-aminopropyl silsesquioxane).,On the other hand,no crystallization of the heteropolyacid was observed in the membranes containing ZrO2,although,denser surface fractal-like structures constituted by the heteropolyacid were observed.},
note = {Online available at: \url{https://doi.org/10.1016/j.jnoncrysol.2005.06.007} (DOI). Prado, L.; Ponce, M.; Funari, S.; Schulte, K.; Haramus, V.; Willumeit, R.; Pereira Nunes, S.: SAXS/WAXS characterization of proton-conducting polymer membranes containing phosphomolybdic acid. Journal of Non-Crystalline Solids. 2005. vol. 351, no. 27-29, 2194-2199. DOI: 10.1016/j.jnoncrysol.2005.06.007}}