@misc{budd_gas_separation_2005, author={Budd, P.M.,Msayib, K.J.,Tattershall, C.E.,Ghanem, B.S.,Reynolds, K.J.,McKeown, N.B.,Fritsch, D.}, title={Gas separation membranes from polymers of intrinsic microporosity}, year={2005}, howpublished = {journal article}, doi = {https://doi.org/10.1016/j.memsci.2005.01.009}, abstract = {When polymeric membranes are employed to remove selectively one component from a gaseous mixture, there is generally a trade-off between selectivity and permeability. Data are presented for two polymers of intrinsic,microporosity, PIM-1 and PIM-7, which show a significant advance across the previous upper bound of performance for commercially important gas pairs including O2/N2 and CO2/CH4. The exceptional properties of PIMs arise from,their rigid but contorted molecular structures, which frustrate packing and so create free volume, coupled with chemical functionality giving strong intermolecular interactions.}, note = {Online available at: \url{https://doi.org/10.1016/j.memsci.2005.01.009} (DOI). Budd, P.; Msayib, K.; Tattershall, C.; Ghanem, B.; Reynolds, K.; McKeown, N.; Fritsch, D.: Gas separation membranes from polymers of intrinsic microporosity. Journal of Membrane Science. 2005. vol. 251, no. 1-2, 263-269. DOI: 10.1016/j.memsci.2005.01.009}}