%0 journal article %@ 0010-938X %A Jiang, P.,Blawert, C.,Scharnagl, N.,Bohlen, J.,Zheludkevich, M. %D 2020 %J Corrosion Science %N %P 108863 %R doi:10.1016/j.corsci.2020.108863 %T Mechanistic understanding of the corrosion behavior of Mg4Zn0.2Sn alloys: from the perspective view of microstructure %U https://doi.org/10.1016/j.corsci.2020.108863 %X The corrosion behavior of as-cast and extruded Mg4Zn0.2Sn (wt.%) alloys was comprehensively compared in 0.5 wt.% NaCl solution. Microstructure and surface chemistry related corrosion performance has been revealed. Zinc-supersaturated solid solution is formed around the intermetallics in the as-cast alloy, but zinc alternately segregates between the α-Mg matrix in the extruded alloy. According to Scanning Kelvin Probe Force Microscopy and immersion tests, micro-galvanic corrosion between the precipitates (intermetallics or impurity particles) or Zinc-rich area and the matrix resulted in severe localized corrosion in both conditions. However, alternation of microstructure induced by extrusion significantly enhanced the corrosion resistance of Mg4Zn0.2Sn alloy.