%0 journal article
%@ 1387-1811
%A Petukhov, D.I.,Eliseev, A.A.,Kolesnik, I.V.,Napolskii, K.S.,Lukashin, A.V.,Tretyakov, Y.D.,Grigoriev, S.V.,Grigorieva, N.A.,Eckerlebe, H.

%D 2008
%J Microporous and Mesoporous Materials
%N 1-3
%P 440-447 
%R doi:10.1016/j.micromeso.2008.01.033
%T Formation mechanism and packing options in tubular anodic titania films
%U https://doi.org/10.1016/j.micromeso.2008.01.033
1-3 
%X Titania nanotube arrays were synthesized via anodic oxidation of titanium foils in glycerol electrolyte containing NH4F at anodization voltage ranging from 10 V to 30 V. The structural parameters of self-organized periodic arrays of titania nanotubes were determined by small-angle neutron scattering and scanning electron microscopy techniques. Transmission electron microscopy and electron diffraction studies of single-standing nanotubes revealed the presence of nanocrystalline titanium oxide phases with oxidation states lower than +4 (TiO, Ti2O3). Several assumptions on growth and self-organization mechanism of nanotube arrays have been made.