%0 journal article %@ 0966-9795 %A Kozlov, A.,Ohno, M.,Abu Leil, T.,Hort, N.,Kainer, K.U.,Schmid-Fetzer, R. %D 2008 %J Intermetallics %N 2 %P 316-321 %R doi:10.1016/j.intermet.2007.10.011 %T Phase equilibria, thermodynamics and solidification microstructures of Mg–Sn–Ca alloys, Part 2: Prediction of phase formation in Mg-rich Mg–Sn–Ca cast alloys %U https://doi.org/10.1016/j.intermet.2007.10.011 2 %X The basis of this work is a detailed investigation of phase equilibria of the Mg–Sn–Ca system for wide ranges of composition and temperature by means of a combined approach of our own key experiments, first-principles calculations of finite-temperature properties of the compounds and Calphad-type modeling. In this report, the generated thermodynamic description is applied to predict the phase formation and discuss the solidification behavior of practically important Mg-rich alloys. Solidification calculations, based on computational thermochemistry and the present dataset, are successfully applied to the analysis of experimentally observed as-cast microstructures and thermal analysis data for the Mg-rich alloy samples.