%0 journal article
%@ 1022-1352
%A Yave, W.,Shishatskiy, S.,Abetz, V.,Matson, S.,Litvinova, E.,Khotimskiy, V.,Peinemann, K.-V.

%D 2007
%J Macromolecular Chemistry and Physics
%N 22
%P 2412-2418 
%R doi:10.1002/macp.200700399
%T A Novel Poly(4-methyl-2-pentyne)/TiO2 Hybrid Nanocomposite Membrane for Natural Gas Conditioning: Butane/Methane Separation
%U https://doi.org/10.1002/macp.200700399
22 
%X Poly(4-methyl-2-pentyne) (PMP)/TiO2 hybrid nanocomposite membranes have been investigated for natural gas conditioning. Tailor-made PMP with 35% cis-content was identified as an attractive material to prepare nanocomposite membranes; it presented good stability towards organic vapors and optimal properties for butane/methane separation. The PMP/TiO2 hybrid nanocomposite membranes presented an improvement of butane permeability and butane/methane selectivity. The addition of TiO2 nanoparticles to the PMP enhanced the selectivity more effectively than fumed-silica, and it is attractively higher than those currently reported in the open literature.