%0 journal article
%@ 0021-9797
%A Bastardo, L.A.,Iruthayaraj, J.,Lundin, M.,Dedinaite, A.,Vareikis, A.,Makuska, R.,Wal, A.van der,Furo, I.,Haramus, V.,Claesson, P.M.

%D 2007
%J Journal of Colloid and Interface Science
%N 1
%P 21-33 
%R doi:10.1016/j.jcis.2006.09.004
%T Soluble complexes in aqueous mixtures of low charge density comb polyelectrolytes and oppositely charged surfactants probed by scattering and NMR
%U https://doi.org/10.1016/j.jcis.2006.09.004
1 
%X A low charge density polyelectrolyte with a high graft density of 45 units long poly(ethylene oxide) side-chains has been synthesized. In this comb polymer, denoted PEO45MEMA:METAC-2, 2 mol% of the repeating methacrylate units in the polymer backbone carry a permanent positive charge and the remaining 98 mol% a 45 unit long PEO side-chain. Here we describe the solution conformation of this polymer and its association with an anionic surfactant, sodium dodecylsulfate, SDS. It will be shown that the polymer can be viewed as a stiff rod with a cross-section radius of gyration of 29 Å. The cross-section of the rod contracts with increasing temperature due to decreased solvency of the PEO side-chains. The anionic surfactant associates to a significant degree with PEO45MEMA:METAC-2 to form soluble complexes at all stoichiometries. A cooperative association is observed as the free SDS concentration approaches 7 mM. At saturation the number of SDS molecules associated with the polymer amounts to 10 for each PEO side-chain. Two distinct populations of associated surfactants are observed, one is suggested to be molecularly distributed over the comb polymer and the other constitutes small micellar-like structures at the periphery of the aggregate. These conclusions are reached based on results from small-angle neutron scattering, static light scattering, NMR and surface tension measurements.