@misc{schoeps_solvent_resistant_2009, author={Schoeps, D.,Dashuk, V.,Ebert, K.,Plenio, H.}, title={Solvent resistant nanofiltration of enlarged (NHC)Pd(allyl)Cl-Complexes for cross coupling reactions}, year={2009}, howpublished = {journal article}, doi = {https://doi.org/10.1021/om900214j}, abstract = {An enlarged imidazolinium salt with a molecular mass of nearly 800 g/mol was synthesized and the respective N-heterocyclic carbene (NHC= N,N’-bis(2,6-diisopropyl-4-CH2NCy2-,phenyl)-4,5-dihydroimidazol-2-ylidene) converted into (NHC)Pd(allyl)Cl and (NHC)Pd(cinnamyl)Cl complexes. The cinnamyl complex displays excellent activities in the,Suzuki-Miyaura coupling and the Buchwald-Hartwig amination. The separation of this complex from the coupling products by means of a solvent resistant nanofiltration using a PDMS (poly-dimethylsiloxane) membrane on PAN (polyacrylonitrile) was tested and very high retention of between 97% and 99.9% of the (NHC)Pd complex observed. The residual Pd content in the cross coupling products is in the range of 3.5 - 25ppm.}, note = {Online available at: \url{https://doi.org/10.1021/om900214j} (DOI). Schoeps, D.; Dashuk, V.; Ebert, K.; Plenio, H.: Solvent resistant nanofiltration of enlarged (NHC)Pd(allyl)Cl-Complexes for cross coupling reactions. Organometallics. 2009. vol. 28, no. 13, 3922-3927. DOI: 10.1021/om900214j}}